$this->_scripts[stuff] = "Go to the object $this, and find the _scripts property of it. In this case, that property is an array, and so it calls for a specific index of that array.
$this->params->get(‘loadMootools’) is actually "Go to the object $this, and find the params property of it. This property is apparantly an object itself, with a method get(), which is called with a string parameter (loadMootools)
=> is used as a key-value pairing identifier.
in this case, it’s in an array definition, assigning the value ‘text/javascript’ to the key $template_baseurl.‘/lib/js/mootools.js.php’. You also often see this notation in foreach statements (foreach ($array AS $key => $value))